Home » Cementing » Gas & Oil Well Cement Properties Guide | 7 Properties

Gas & Oil Well Cement Properties Guide | 7 Properties

Cementing is the most important non-drilling function performed by the Drilling Foreman as poor cementing properties & techniques used in oil and gas well can cause countless drilling problems if the bottom joint of surface pipe is lost.  It can also cause costly remedial operations or loss of hole.  A bad cement job can make an  otherwise sound  investment a  disaster.  Loss  of  control  means  loss  of  reserves and reduction in the potential of secondary recovery operations.

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Oil & Gas Well Cement Functions

Cement has three functions.

  • The first and most important function of the cement slurry is to carry all of the worlds trash (we call it additives) a mile or two under the ground and dispose of it.  
  • The cement must also be capable of supporting the casing.  
  • And finally, the cement must adequately isolate the intervals of interest.   

All cementing design considerations should be directed at these functions. In addition to that, the Drilling Foreman should be concerned with accomplishing these functions as simply and economically as possible. In order to function in this capacity we must become fundamentally familiar with the oil well-cementing properties.

Gas & Oil Well Cementing Properties

Cements have various properties that are important to drilling personnel in the oil & gas rigs, such properties are as following:

  • Viscosity.
  • Thickening time.
  • Density.
  • Yield.
  • Fluid loss.
  • Free water.
  • Compressive strength.

Oil well cement Viscosity

Actually, the viscosity property of cement is normally 40-75 funnel seconds used in oil wells. Cement is a non-Newtonian fluid and is shear thinning. In other words, the cement gets thinner as the shear rate (velocity) increases. Accordingly, The Bingham Plastic and the Power Law Models can be used to describe the viscosity of cement at various shear rates; however, the Power Law Model is more accurate.

Viscosity is important when considering displacement mechanics.   Low viscosity cement will have better displacement properties at higher flow rates, while high viscosity oil well cement may have better displacement properties at lower flow rates.

How to Control The Cement Viscosity

Viscosity is controlled by the amount of water added to the cement.  Only 25% water by weight of cement is required for hydration, but more water is added to provide for pumpability. Dispersants lower the yield point (check also Yield Point In Drilling Mud Formula) of cement slurries reducing friction and allowing turbulence to occur at lower pump rates.  Using dispersants allows the cement to be mixed with less water yielding higher densities.

Cement Thickening Time Property

In general, the thickening time of cement can vary anywhere from 20 minutes to days depending upon pressure, temperature, additives, and how the cement is mixed. Published values for this oil well cement property are based on the API Standards for Temperature in Table 2. Thickening time tests should be run for actual well conditions when the conditions vary from the API standards.

WELL DEPTH (feet)BOTTOM-HOLE STATIC TEMPERATURE (°F)BOTTOM-HOLE CIRCULATING TEMPERATURE (casing)BOTTOM-HOLE CIRCULATING TEMPERATURE (squeeze)
  2,000  110  91  98
  4,000  140  103  116
  6,000  170  113  137
  8,000  200  125  159
10,000  230  144  186
 12,000  260  172  213
 14,000  290  206  242
 16,000  320  248  271
 18,000  380  340  —
Table 2. Basis of API Testing Schedules for Standardization Purposes

Thickening time tests are run in a pressurized consistometer as shown in Figure 1. In fact, you should remember that a pressurized metal container does not always simulate down-hole conditions.  If some of the mixed water is lost to a permeable formation through filtration, then the pumping time can be less than anticipated. Interruptions in pumping the cement can also cause a reduction in the thickening time.  If the oil well cement is allowed to sit for a while, the thickening time property values are no longer applicable.  The actual mixed water from the location should be used in the thickening time tests whenever possible

Oil Well Cement Properties Guide - Pressurized Consistometer
Figure 1 : Schematic of a Typical Pressurized Consistometer – Oil well cement properties
1

Cement Thickening Time Planning

Planned thickening times should allow ample time to place the cement plus enough time should any unexpected problems occur.  However, thickening times should not be excessive.  Waiting on cement (WOC) to set before resuming drilling operations can be costly especially in high day rate operations.   Excessive thickening time can also allow settling and separation of slurry components, loss of hydrostatic head resulting in gas cutting, and formation of free water pockets.

Reducing Cement Thickening Time

Cementers can easily reduce thickening times by adding accelerators such as calcium chloride. The temperature of the mix water is also important particularly with accelerated cement, figure 2 shows the effect of temperature on cement thickening time properties.  The thickening time for Class A with two percent calcium chloride is ten hours at 60 degrees but reduces to 4 hours at 80 degrees. Increasing pressure will shorten the thickening time although its effects are less pronounced than temperature.

Increasing Cement Thickening Time

By adding Retarders we can increase thickening time, but at the same time extenders reduce density.  Adding more mix water will increase the thickening time with unretarded cement but this may not be the case with retarded cement.  The additional water can dilute the retarder concentration and therefore its effectiveness.

 Effect of Temperature on Thickening Time - oil cement property
Figure 2. Effect of Temperature on Thickening Time

Cement Density

The density of cement can vary from less than 8.33 ppg for foamed cement to as much as 20 ppg for densified slurries.  Cement densities properties in oil & gas wells need to be varied to prevent lost circulation or to control abnormal formation pressures.

Normal densities for API cement are shown in Table 3. As you can see, the density can be varied by altering the water content; however, care should be taken to avoid excess water. In general, too much water will increase the thickening time and reduce the strength of the cement.

Controlling Cement Density

We always can decrease the density by adding extenders such as pozzolans and bentonite but you should remember that the extenders require more mix water. In addition to that, density can be increased by adding weight materials such as barite and hematite.

API CLASSWATER (gals/sk)DENSITY (ppg)YIELD (ft3/sk)
A5.215.61.18
B5.215.61.18
C6.314.81.32
D4.316.41.06
E4.316.41.06
G5.015.81.15
H4.316.41.06
Table 3. Normal Water Requirements and Densities for
Neat API Slurries from Halliburton Red Book – Oil well cement properties

Slurry Yield

The yield is the volume of cement mixture created per sack of initial cement. The yield can vary significantly depending upon the additives.  As illustration slurry yields can be as little as 0.90 ft3 per sack for densified cement to 4.70 ft3 per sack for a pozzolan, cement, and bentonite mix.  Table 3 shows the yields for various API cement when the normal mix water is used.

Fluid Loss Of Cement

This oil well cement property (API fluid loss) test is conducted at 100 psi differential through a 325 mesh screen.  The fluid loss for Class A neat cement will exceed 1,000 ml.  The API well simulation test is run at various elevated temperatures and a pressure differential of 1,000 psi through a 325 mesh screen.  The testing procedures can be found in API Spec 10.  Whenever fluid loss tests are reported, the temperature and differential pressure should be included.

Decreasing Cement Fluid Loss

Usually, bentonite or high molecular weight polymers are added to the cement to reduce the fluid loss property. But the fluid loss additives are temperature dependent and will lose some effectiveness at higher temperatures like some polymers which will even break down at high temperatures.

Common Cement Fluid Loss Values

Reported optimum values for fluid loss varies considerably using the API well simulation test at the bottom hole circulating temperature. For a typical casing job, recommended fluid loss values range from a maximum of 100 ml to no control.  The recommended API fluid loss ranges from 50 to 250 ml for liners and 50 to 200 ml for squeeze cementing. The literature also recommends that the fluid loss be kept below 150 ml when annular gas flow is a problem. For most applications, a fluid loss of 200 ml is adequate.

Free Water

Free water is caused by the separation of the mix water and cement solids. Surely, all neat cement will have some free water which can contribute to annular gas flows. For example, In deviated and horizontal wells the separated mix water will migrate to the high side of the hole and cause a channel.  In fact, the cement-free water content property in directional gas and oil wells or wells with annular gas flow problems shall equal zero. Recommended free water content for most vertical casing jobs is less than one percent.  The addition of fluid loss additives or 0.1% to 0.2% bentonite will reduce the free water content to near zero.

Cement Compressive Strength

When cement sets, it develops a compressive strength over time which is considered as a function of time, temperature, and pressure. As an illustration, Figure 3 is a graph of the 24-hour compressive strength for various cement versus pressure at 200°F. Above 3,000 psi, there is very little change in compressive strength as the pressure increases. All API compressive strength tests are run at 3,000 psi when the depth is below 4,000 feet since there is little change in the expected compressive strength. Moreover, The  API  Spec  10  has pressure and temperature schedules for compressive strength tests based upon depth and anticipated temperature gradient.

Twenty-Four Hour Compressive Strength versus Pressure
Figure3: Twenty-Four Hour Compressive Strength versus Pressures Cured at 200 o
F – oil well cement properties

Neat cement will attain the highest compressive strengths. Usually, the compressive strength will be near the maximum within 72 hours. Extenders and using more mix water will decrease the ultimate compressive strength. At the same time, densifying a slurry by using the minimum mix water will increase the ultimate compressive strength.  At the same temperature, accelerated cement will attain a higher compressive strength quicker than neat cement and retarded cement.

Common Cement Compressive Strength

For most oil field applications, a cement compressive strength property of 500 psi is sufficient. A lot of filler cement has compressive strengths of 500 psi with relatively low densities and higher yields. Filler cement is less expensive than neat slurries. Thus, neat cement is placed across the producing formations and behind the shoe joint, and filler cement is used to fill the remainder of the annular capacity space that requires cement.

Cement Compressive Stength Tests

All compressive strength tests should be run by the service company prior to the actual cementing job.  In critical situations, the actual cement composition and mix water should be used at simulated downhole conditions to determine compressive strength.   In development areas, compressive strength can be spot-checked where the same cementing mixture is being used on similar wells.  There is no need to run lab tests for each well.  In the field, dry cement samples should be collected in the advent a cementing problem occurs.  Lab tests with the dry samples can be used to investigate the problem.

Effect Of Temperature on Cement Compressive Stength

At high temperatures oil & gas wells, cement can suffer from strength retrogression which is a loss in compressive strength property with time. It is also has been reported that above 230°F there is a pronounced decrease in compressive strength and increase in permeability of many commonly used cementing materials.  In general, additives that are not chemically reactive with the cement and which require a high water to cement ratio produce cement of poor temperature stability. (Bentonite is probably the worst offender and should not be used in any composition in excess of 4% by weight of the cement when temperatures are expected to exceed 230°F.)

Controlling Cement Compressive Strength

The addition of 35 to 40 percent silica flour will inhibit strength retrogression.  Table 4 shows the increased strength of Class “B” and 50-50 Poz with 30 and 40 percent silica flour.  Neat cement without silica flour would have compressive strengths of less than 1,000 psi depending upon the bottom hole temperature. Also, Silica mix with Portland cement can be used to temperatures around 750°F.  As with any critical cementing operation, the properties of the proposed cement mixture should be checked in the lab at downhole conditions in gas & oil wells.   For very high temperatures, strength retrogression should be added to the list of properties to check.

                   CEMENT  SILICA FLOUR (%) CURED 7 DAYS (°F) 80 CURED 7 DAYS (°F) 100 HEATED 7 DAYS (°F) 400 HEATED 7 DAYS (°F) 500HEATED 7 DAYS (°F) 600
Class “B”  30  1,400  1,985  6,600  4,450  2,600
Class “B”  40  1,215  1,810  6,550  6,300  5,920
  POZ  30  560  1,225  4,200  4,850  6,000
  POZ  40  775  1,240  3,400  4,200  5,850
Table 4. Effects of Temperature on Compressive Strength

Table 5 shows how the compressive strength will change with the addition of silica flour for class G cement.   The samples were cured at 440°F for three and seven days and then cured at 725°F for 3 days.

Calcium aluminate cement

Calcium aluminate cement (usually termed cement fondue or limonite) can be used in applications where the temperature is expected to exceed 700°F such as in-situ combustion wells where the temperature may reach 2,000°F.  Calcium aluminate cement is manufactured from limestone and bauxite ore.  Neat cement will have a density of 14.7 to 15.8 ppg and will attain a compressive strength of as much as 12,000 psi in 24 hours.

SILICA FLOUR (%)COMPRESSIVE STRENGTH (3 days)COMPRESSIVE STRENGTH (7 days)
  0  545  425
  40  11,025  10,010
Table 5. Effects of Temperature on Class G Cement with Silica Flour

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